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Sodium hydrazoate, NaN3

The Sodium hydrazoate, NaN3 is formed by neutralizing hydrazoic acid with sodium hydroxide; by the interaction of sodamide and nitrous oxide:



and by decomposing hydrazoyl chloride with sodium hydroxide:

N3Cl+2NaOH =NaN3+NaOCl+H2O.

Sodium hydrazoate forms colourless crystals, which melt without decomposition, but explode at a temperature higher than the melting-point. At 10° C. 100 grams of water dissolve 40.16 grams, at 17° C. 41.7 grams.

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